Difference between WCF and Web service

Web Service in ASP.NET

A Web Service is programmable application logic accessible via standard Web protocols. One of these Web protocols is the Simple Object Access Protocol (SOAP). SOAP is a W3C submitted note (as of May 2000) that uses standards based technologies (XML for data description and HTTP for transport) to encode and transmit application data.
Consumers of a Web Service do not need to know anything about the platform, object model, or programming language used to implement the service; they only need to understand how to send and receive SOAP messages (HTTP and XML).

WCF Service

Windows Communication Foundation (WCF) is a framework for building service-oriented applications. Using WCF, you can send data as asynchronous messages from one service endpoint to another. A service endpoint can be part of a continuously available service hosted by IIS, or it can be a service hosted in an application. An endpoint can be a client of a service that requests data from a service endpoint. The messages can be as simple as a single character or word sent as XML, or as complex as a stream of binary data.
In what scenarios must WCF be used

• A secure service to process business transactions.
• A service that supplies current data to others, such as a traffic report or other monitoring service.
• A chat service that allows two people to communicate or exchange data in real time.
• A dashboard application that polls one or more services for data and presents it in a logical presentation.
• Exposing a workflow implemented using Windows Workflow Foundation as a WCF service.
• A Silverlight application to poll a service for the latest data feeds.

Features of WCF

• Service Orientation
• Interoperability
• Multiple Message Patterns
• Service Metadata
• Data Contracts
• Security
• Multiple Transports and Encodings
• Reliable and Queued Messages
• Durable Messages
• Transactions
• AJAX and REST Support
• Extensibility 

Difference between Web Service in ASP.NET & WCF Service

Web service is a part of WCF. WCF offers much more flexibility and portability to develop a service when comparing to web service. Still we are having more advantages over Web service, following table provides detailed difference between them.

Features	Web Service	WCF
Hosting	It can be hosted in IIS	It can be hosted in IIS, windows activation service, Self-hosting, Windows service
Programming	[WebService] attribute has to be added to the class	[ServiceContraact] attribute has to be added to the class
Model	[WebMethod] attribute represents the method exposed to client	[OperationContract] attribute represents the method exposed to client
Operation	One-way, Request- Response are the different operations supported in web service	One-Way, Request-Response, Duplex are different type of operations supported in WCF
XML	System.Xml.serialization name space is used for serialization	System.Runtime.Serialization namespace is used for serialization
Encoding	XML 1.0, MTOM(Message Transmission Optimization Mechanism), DIME, Custom	XML 1.0, MTOM, Binary, Custom
Transports	Can be accessed through HTTP, TCP, Custom	Can be accessed through HTTP, TCP, Named pipes, MSMQ,P2P, Custom
Protocols	Security	Security, Reliable messaging, Transactions